Foundations
Module 2 of 6 · Foundations

UN numbers — the 4-digit 'name tag'

Every dangerous good has a unique 4-digit UN number — petrol = UN1203, sulphuric acid = UN1830.

ADR 2025 · 3.2.1
Friendly introduction & study aid. Not the official ADR certificate. The legal certificate comes from a DfT/SQA-approved training centre and the SQA exam.
Draft beginner content — pending review by a qualified DGSA

Lessons

Violet · Lesson

What a UN number is

15s ADR 2025 · 3.1.2 / 3.2.1

Every dangerous substance in the world is given a 4-digit 'UN number' so it can be identified the same way everywhere — on a lorry in Britain, a ship leaving Rotterdam or a parcel landing in Dubai. The 'UN' stands for United Nations. Petrol is UN1203. Sulphuric acid is UN1830. Lithium-ion batteries are UN3480. The UN number is like a name tag the whole world agrees on.

A UN number is a 4-digit ID for a substance.
Key points
  • Same number worldwide — UN1203 = petrol everywhere.
  • Used on paperwork, package marks and tanker plates.
ADR Citation
ADR 2025 · 3.1.2 / 3.2.1
Each entry in the Dangerous Goods List (ADR Part 3, Table A) has a UN number and a proper shipping name; these uniquely identify the substance for transport.
Draft content, pending DGSA review. Verify against the cited clause before relying on it.
Violet · Lesson

Three you'll see a lot

10s UN1203 petrol UN1830 acid UN3480 batteries ADR 2025 · 3.2.1 Table A
ADR hazard class 3 — FlammableUN1203 petrol
ADR hazard class 8 — CorrosiveUN1830 acid
9UN3480 batteries

Classes 6.1, 7 and 9 use illustrative placeholders until official artwork is supplied.

Three real UN numbers you'll meet again and again in this app — and in real life: UN1203 = petrol (motor spirit) — Class 3 flammable liquid. UN1830 = sulphuric acid — Class 8 corrosive. UN3480 = lithium-ion batteries — Class 9 miscellaneous. Don't try to memorise them yet; just know they're real, fixed and worldwide.

UN1203 = petrol — Class 3 (flammable liquid).
Key points
  • UN1830 = sulphuric acid — Class 8 (corrosive).
  • UN3480 = lithium-ion batteries — Class 9 (misc.).
ADR Citation
ADR 2025 · 3.2.1 Table A
ADR Table A (Dangerous Goods List) lists each UN entry with its proper shipping name, class, packing group, labels, quantity provisions and tunnel code.
Draft content, pending DGSA review. Verify against the cited clause before relying on it.
Violet · Lesson

Don't confuse it with other codes

15s ADR 2025 · 3.2.1

Lots of numbers float around in transport. A UN number is always 4 digits, often written as 'UN1203'. It's NOT a postcode, a delivery time, an ISO standard or a vehicle plate. If a colleague says 'this is UN-stuff', they probably mean a UN number — that 4-digit substance ID. When in doubt, look it up in the Dangerous Goods List (ADR Table A).

A UN number is always 4 digits, e.g. UN1203.
Key points
  • Not a time, postcode, ISO standard or vehicle plate.
  • Look up unknowns in ADR Table A (3.2.1).
ADR Citation
ADR 2025 · 3.2.1
The Dangerous Goods List in 3.2.1 is the master register of UN numbers and their proper shipping names.
Draft content, pending DGSA review. Verify against the cited clause before relying on it.

Practice questions

0 / 4 answered
  1. 1
    Which of these is a UN number?
  2. 2
    How many digits does a UN number have?
  3. 3
    What is the UN number for petrol (motor spirit)?
  4. 4
    Why is a UN number useful?
Practice quiz — pick an answer to see whether it's right and why.